Residue‐Selective C−H Sulfenylation Enabled by Acid‐Activated <i>S</i> ‐Acetamidomethyl Cysteine Sulfoxide with Application to One‐Pot Stapling and Lipidation Sequence
نویسندگان
چکیده
The aromatic (C−H) sulfenylation reaction with S-acetamidomethyl cysteine sulfoxide (Cys(Acm)(O)) can be Trp- or Tyr-selective under acidic conditions. red chloride anion team kicks the Cys(Acm)(O) ball into Trp goal, whereas blue trimethylsilyl Tyr goal. proton scoreline in stands supports both teams. More information found Research Article by A. Otaka and co-workers (DOI: 10.1002/chem.202300799).
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ژورنال
عنوان ژورنال: Chemistry: A European Journal
سال: 2023
ISSN: ['0947-6539', '1521-3765']
DOI: https://doi.org/10.1002/chem.202301087